论文标题
对电化学氢设备中质子传导锆石的应用,前景和挑战的综述
A Review of Applications, Prospects, and Challenges of Proton-Conducting Zirconates in Electrochemical Hydrogen Devices
论文作者
论文摘要
将来,当化石燃料耗尽时,替代能源对于日常需求至关重要。基于氢的能量在这方面可以发挥至关重要的作用。这种能量是绿色,干净且可再生的。 Ele-Trochemical氢设备已在核电站广泛使用,以管理基于氢的可再生燃料。在这些电化学设备中,掺杂的锆酸盐材料通常用作电解质。这些材料具有出色的物理稳定性和高质子的传输数量,这使其适合多种应用。掺杂增强了锆酸盐材料的物理和电子特性,使其非常适合实际应用。这篇评论强调了基于锆酸盐的pro-to-docductuction材料在电化学细胞中的应用,尤其是在tri剂量监测器,trimentium恢复,氢传感器和氢气泵系统中的应用。这篇综述的中央部分总结了最近的研究,并提供了对各种兴奋剂方案,实验设置,仪器,最低操作条件,形态,组成和锆电电解质材料性能的全面见解。此外,讨论了阻碍锆石材料在ELEC型氢设备中的全部潜力的不同挑战。最后,本文为希望在该领域进行研究的有抱负者提供了一些途径。
In the future, when fossil fuels are exhausted, alternative energy sources will be essential for everyday needs. Hydrogen-based energy can play a vital role in this aspect. This energy is green, clean, and renewable. Elec-trochemical hydrogen devices have been used extensively in nuclear power plants to manage hydrogen-based renewable fuel. Doped zirconate materials are commonly used as an electrolyte in these electrochemical devices. These materials have excellent physical stability and high proton transport numbers, which make them suitable for multiple applications. Doping enhances the physical and electronic properties of zirconate materials and makes them ideal for practical applications. This review highlights the applications of zirconate-based pro-ton-conducting materials in electrochemical cells, particularly in tritium monitors, tritium recovery, hydrogen sensors, and hydrogen pump systems. The central section of this review summarizes recent investigations and provides a comprehensive insight into the various doping schemes, experimental setup, instrumentation, op-timum operating conditions, morphology, composition, and performance of zirconate electrolyte materials. In addition, different challenges that are hindering zirconate materials from achieving their full potential in elec-trochemical hydrogen devices are discussed. Finally, this paper lays out a few pathways for aspirants who wish to undertake research in this field.