论文标题

有效的流体动力半径不是常数

The effective hydrodynamic radius is not a constant

论文作者

Ren, Gan

论文摘要

通常假定有效的流体动力半径是通过其变体测试Stokes-Einstein关系的常数。我们已经使用正苯基和KOB-Andersen模型进行了分子动力学模拟,以检查假设,并发现有效的流体动力半径不是恒定的,但随着温度降低而降低。 Stokes-Einstein关系的变体未建立,但是Stokes-Instein关系通过考虑有效的水动力半径的变化是有效的。我们建议在使用变体测试Stokes-Einstein关系时认真评估假设。

The effective hydrodynamic radius is usually assumed to be a constant in testing the Stokes-Einstein relation by its variants. We have performed molecular dynamics simulations with ortho-terphenyl and Kob-Andersen model to examine the assumption and found the effective hydrodynamic radius is not a constant but decreases with decreasing temperature. The variant of Stokes-Einstein relation is not established but Stokes-Einstein relation is valid by considering the changes of the effective hydrodynamic radius. We propose the assumption should be seriously evaluated when using variants to test Stokes-Einstein relation.

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