学术文献库

The similarity in atomic structure between liquids and glasses has stimulated a long-standing hypothesis that the nature of glasses may be more fluid like, rather than an apparent solid. In principle, the nature of glasses can be characterized by measuring the dynamic response of rheology to shear strain rate in the glass state. However, limited by the brittleness of glasses and current experimental techniques, the dynamic behaviors of glasses were mainly assessed in the supercooled liquid state or in the glass state within a narrow rate range. Therefore, the nature of glasses has not been well elucidated experimentally. Here we report the dynamic response of shear stress to shear strain rate of metallic glasses over nine orders of magnitude in time scale, equivalent to hundreds of years, by broadband stress relaxation experiments. The full spectrum dynamic response of metallic glasses, together with other glasses including silicate and polymer glasses, granular materials, soils, emulsifiers and even fire ant aggregations, follows a universal scaling law within the framework of fluid dynamics. Moreover, the universal scaling law provides comprehensive validation of the conjecture on the jamming phase diagram by which the dynamic behaviours of a wide variety of glass system can be unified under one rubric parameterized by thermodynamic variables of temperature, volume and stress in trajectory space.