学术文献库

Despite the omnipresence of colloidal suspensions, little is known about the influence of shape on phase transformations, especially in nonequilibrium. To date, real-space imaging results are limited to systems composed of spherical colloids. In most natural and technical systems, however, particles are non-spherical and their structural dynamics are determined by translational and rotational degrees of freedom. Using confocal microscopy, we reveal that suspensions of ellipsoidal colloids form an unexpected state of matter, a liquid glass in which rotations are frozen while translations remain fluid. Image analysis unveils hitherto unknown nematic precursors as characteristic structural elements of this state. The mutual obstruction of these ramified clusters prevents liquid crystalline order. Our results give unique insight into the interplay between local structures and phase transformations. This helps to guide applications such as self-assembly of colloidal superstructures and also gives first evidence of the importance of shape on the glass transition in general.